You use the preboot execution environment (PXE) to boot a host and start the ESXi installer from a network interface.
ESXi 6.0 is distributed in an ISO format that is designed to install to flash memory or to a local hard drive. You can extract the files and boot by using PXE.
PXE uses Dynamic Host Configuration Protocol (DHCP) and Trivial File Transfer Protocol (TFTP) to boot an operating system over a network.
PXE booting requires some network infrastructure and a machine with a PXE-capable network adapter. Most machines that can run ESXi have network adapters that can PXE boot.