Use the esxcli commands to manage the PSA multipathing plug-ins and storage paths assigned to them.
You can display all multipathing plug-ins available on your host. You can list any third-party MPPs, as well as your host's NMP and SATPs and review the paths they claim. You can also define new paths and specify which multipathing plug-in should claim the paths.
For more information about commands available to manage PSA, see the Getting Started with vSphere Command-Line Interfaces.